University of Basel researchers have reached an important milestone in their quest to produce more sustainable luminescent materials and catalysts for converting sunlight into other forms of energy. Based on the cheap metal manganese, they have developed a new class of compounds with promising properties that until now have primarily been found in noble metal compounds.
Smartphone screens and catalysts for artificial photosynthesis – to produce fuels from sunlight, for example – often contain very rare metals. Iridium, for instance, which is used in organic light-emitting diodes (OLEDs), is rarer than gold or platinum. Ruthenium, used in solar cells, is also one of the rarest stable elements. These metals are not only very expensive, by virtue of their scarcity, but also toxic in many compounds.
Now, a team led by Professor Oliver Wenger and his doctoral student Patrick Herr from the University of Basel have for the first time succeeded in producing luminescent manganese complexes in which exposure to light causes the same reactions to take place as in ruthenium or iridium compounds. The findings have been published in the journal Nature Chemistry. The advantage of using manganese is that the element is 900,000 times more abundant in the Earth’s crust than iridium, as well as being significantly less toxic and many times cheaper.
At present, the new manganese complexes perform worse than iridium compounds in terms of their luminous efficiency. However, the light-driven reactions that are needed for artificial photosynthesis such as energy- and electron-transfer reactions take place at high speed. This is due to the special structure of the new complexes, which leads to an immediate charge transfer from the manganese toward its direct bonding partners on excitation with light. This design principle for complexes is already used in certain types of solar cells, although until now it has mostly featured noble metal compounds, and sometimes complexes based on the less noble metal copper.